Cu对Pt/Cu-Mg-Al-O催化剂上NO_x储存性能的影响
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【英文篇名】 Influence of Cu on NO_x Storage Performance of Pt/Cu-Mg-Al-O Catalysts Derived from Hydrotalcites 1 [- m# a; H! A
【作者】 康守方; 蒋政; 郝郑平; - X+ G& S8 ]/ M
【英文作者】 KANG; Shou Fang JIANG; Zheng HAO; Zheng Ping( Research Center for Eco Environmental Science; Chinese Academy of Sciences; Beijing 100085);
, t8 d5 {( C5 L& I! Z【作者单位】 中国科学院生态环境研究中心;
$ G- j5 \& I/ V2 I/ }0 o【刊名】 物理化学学报 , Acta Physico-chimica Sinica, 编辑部邮箱 2005年 03期 & @& R4 |/ g; O& B
期刊荣誉:中文核心期刊要目总览 ASPT来源刊 CJFD收录刊
, h& u& E3 \7 C# h【关键词】 氮氧化物; 水滑石; NO_x储存; 贫燃; Pt/Cu-Mg-Al-O; 1 Z+ u8 z9 a' p$ N! B# ^
【英文关键词】 Nitrogen oxide; Hydrotalcite; NOx storage; Lean burn; Pt/Cu Mg Al O; 5 E6 H: G1 b7 ^: _) O
【摘要】 固定二价与三价阳离子摩尔比为3∶1,采用共沉淀法合成系列Cu-Mg-Al水滑石,经500℃焙烧制成复合氧化物Cu-Mg-Al-O(wCuO(%)分别为0、5、10、20,简称w-CMAO,w=0、5、10、20).通过浸渍法制备Pt/Cu-Mg-Al-O负载型复合氧化物催化剂.XRD结果表明Cu在催化剂及其前驱体中高度分散.采用等温NOx储存实验研究催化剂对NOx的储存性能,NOx-TPD法考察储存的NOx脱附情况.实验结果表明,尽管Cu取代减少了催化剂中MgO含量,但增强了催化剂的NO氧化活性,有效提高了催化剂的NOx储存性能.同时TPD结果进一步表明当CuO掺杂量在w=(10~20)%时,可以明显降低催化剂上生成的硝酸盐的分解温度. 0 M+ g( L4 a* D: t: F, h
【英文摘要】 A series of Cu Mg Al hydrotalcite compounds with M (II) :Al(III) molar ratio of 3 :1 were prepared by co precipitation method.Corresponding mixed oxides were obtained after calcination 500 ℃ ( wCuO(% )= 0,5,10,20,denoted as w CMAO,w=0,5,10,20) .Pt/Cu Mg Al O catalysts were prepared by impregnation with H2PtCl6 solution.XRD results showed that Cu was well dispersed in the catalysts and their precursors.NOx storage performance was investigated using NOx adsorption experiment at constant te... |